The aluminum industry, through the
International Aluminium Institute (IAI),
has developed a number of objectives
for improvement in the environmental
performance of its production facilities.
The IAI measures performance
against these objectives on an annual
basis. The latest data indicates that the
industry, while doubling production
since 1990, has reduced its emissions
of perfluorocarbon greenhouse gases
by almost 80% over the same period.
However, the largest potential for emission
reduction is through the use of
aluminum products in energy-saving
applications, such as lightweight vehicles,
green buildings, and packaging
that protects food and medicines, as
well as through the recycling of these
products at the end of their useful life.
INTRODUCTION
The global aluminum industry has
a well-established sustainability initiative,
“Aluminium for Future Generations,”
overseen by the International
Aluminium Institute (IAI), whose directors
include senior executives from
major global aluminum producers. The
27 IAI member companies represent
over 80% of global primary aluminum
production. The Aluminium for Future
Generations initiative is built on 14 voluntary
objectives, covering sustainability
issues along the value chain, including
not only environmental impacts of
production processes, but also benefits
associated with the use, reuse, and recycling
of aluminum products. The incorindustry’s
performance toward these
quantitative objectives is measured annually
against a set of sustainable development
indicators. Annual results
are assessed through surveys of both
IAI members and non-members and
are available through the IAI website.1
Reduction of greenhouse gas (GHG)
emissions was one of the first voluntary
objectives formulated by the institute,
specifically the reduction of emissions
of CF4 and C2F6, two perfluorocarbon
(PFC) compounds that are emitted periodically
during primary aluminum
production upset conditions known as anode effects. While major progress
has been achieved by the industry in
this area, achieving even greater PFC
emissions reduction remains one of the
strongest focus areas of the Aluminium
for Future Generations initiative.
HOW WOULD YOU... |
…describe the overall significance
of this paper?
The latest (2009) data shows that
the primary aluminum industry
has not only reduced its absolute
perfluorocarbon greenhouse gas
(GHG) emission inventory over
the past 20 years while doubling
production, but offers, through the
use of its products in energy-saving
applications and recycling, even more
significant emission reductions. The
aluminum industry’s global sectoral
approach to climate change has seen
improvements in performance across
a wide range of metrics.
…describe this work to a
materials science and engineering
professional with no experience in
your technical specialty?
This paper delivers the latest (2009)
sustainability performance data
from the primary aluminum industry,
against a number of voluntary
objectives for improvement in,
among other metrics, process energy
effi ciency and GHG emissions
reduction. Changes in the technology
mix of smelters over the past 2
decades have driven improvements in
absolute PFC emission performance,
coincident with a shift in the industry
to new areas of production. |
GREENHOUSE GAS
MONITORING AND REPORTING INFRASTRUCTURE
To assure reliable and accurate reporting
of greenhouse gas emissions
the industry, working collaboratively
with U.S. Environmental Protection
Agency (EPA), the Intergovernmental
Panel on Climate Change (IPCC),
World Resources Institute, and World
Business Council for Sustainable Development,
has developed a set of
protocols and procedures for the measurement,
accounting, and reporting of
greenhouse gases from the aluminum
sector. The Protocol for Measurement
of Tetrafluoromethane (CF4) and
Hexafl uoroethane (C2F6) Emissions
from Primary Aluminum Production2
describes specific procedures for obtaining
reliable measurement results
for PFC emissions from primary aluminum
production. The methodology
has been used to make over 150 direct
PFC emissions measurements in smelters
worldwide. The IPCC references
the PFC measurement protocol in its
highest accuracy Tier 3 method for developing
inventories of PFC emissions
from primary aluminum production.
The smelter measurement data has also
been used to develop the IPCC Tier 2
equation technology-specific coefficients, from which PFC emission rates
are calculated for smelters where no
measurements have yet been made.3
Finally, business level inventory procedures
have been developed which incorporate the PFC measurement protocol
and the IPCC good practices to develop
combined corporate GHG inventories4,5
that include both PFC emissions and
carbon dioxide (and other combustion-related
greenhouse gas) emissions from
production operations.
IAI GREENHOUSE GAS REDUCTION OBJECTIVE
The reduction of PFC emissions was
one of the earliest voluntary objectives
developed by the IAI. Adopted almost
a decade ago, the specific objective was
an 80% reduction in PFC emissions
per metric ton aluminum produced by
2010 from a 1990 baseline. This objective
was surpassed ahead of schedule
in 2006, the result of strong growth in
demand for aluminum products and
resulting investment by the industry in
new, modern, low-emitting smelting
capacity. The response of the IAI directors
was to adopt an even more stringent
objective, with key components as
follows:
- Following the successful achievement
of the global goal for an 80%
reduction in PFC emissions per
metric ton of primary aluminum
produced by 2006 (from the 1990
baseline), the aluminum industry
will further reduce global emissions
of PFCs per metric ton of
aluminum by at least 50% by 2020
as compared to 2006.
- The primary aluminum industry
seeks to achieve the long term
elimination of PFC emissions.
- Coverage of the annual survey of
PFC emissions from IAI member
and non-member aluminum producers
has almost doubled from a
global aluminum production of 12
Mt in 1990 to 22 Mt (60% of the
industry’s production) in 2009. IAI
is striving to increase the global
aluminum production coverage of
its annual surveys to over 80%.
- Based on IAI annual surveys results,
by 2020 IAI member companies
commit to operate with PFC
emissions per metric ton of production
no higher than the 2006 global
median level for their technology
type.
- Progress will be monitored and
reported annually and reviewed
periodically by a recognized and
independent third party. Interim reviews
will ensure progress toward
achieving the 2020 objective.
ANODE EFFECT SURVEY
AND PFC EMISSIONS
REDUCTION RESULTS
The IAI conducts an annual global
survey of primary aluminum producers
(both IAI members and non-members)
for anode effect performance.6 The
survey asks for the average frequency
and duration of anode effects occurring
on smelter potlines in addition to aluminum
production data over the same
period. Average potline overvoltage is
requested from facilities operating with
Rio Tinto Alcan AP technology that relate
potline overvoltage (as opposed to
“anode effect” frequency and duration)
to PFC emissions. The survey also asks
if facility-specific PFC measurements
have been made that allow the use of
IPCC Tier 3 methodology, which produces
significantly better accuracy in
calculating PFC emission rates than the
(technology-specific) Tier 2 methodology.
Survey returns are used to calculate
emission rates for each reporting
facility. Total emissions of CF4 and
C2F6 are calculated by multiplying the
calculated emission rates, kilograms of
CF4 and C2F6 per metric ton aluminum
produced, by the production levels. The
sum of the two PFC emissions is then
calculated as carbon dioxide equivalent
(CO2-e) emissions by multiplying each
PFC emission by its global warming
potential (GWP). Although more recent
GWP values are available, IPCC Second
Assessment Report GWP values
are used for consistency with UNFCCC
reporting7 and for tracking performance
consistently over time from the 1990
baseline. Respondents are asked to
classify their production technology as
one of fi ve types, for purposes of the
survey: bar broken center work prebake
(CWPB), point fed center work prebake
(PFPB), side work prebake (SWPB),
vertical stud Søderberg (VSS), or horizontal
stud Søderberg (HSS). Median
emissions, as metric tons CO2-e/metric
ton aluminum, are calculated for each
of these technology types. These median
emission levels are used to estimate
the PFC emissions from the share of
primary production outside China that
did not participate in the anode effect
survey in a given year (6% in 2009), by
multiplying available production data
for these facilities by the median PFC
emission rate for their technology type.
For Chinese producers a different
methodology is used to estimate PFC
emissions for non-survey participants.
Through 2008 and 2009 there were a
number of direct PFC measurements
made at Chinese production facilities
sponsored by the Asia Pacific Partnership
on Clean Development and
Climate8 as well as additional measurements
made by Chinese researchers
from the Zhengzhou Light Metals
Research Institute (www.rilm.com.cn/english/main_en.asp). As a result of a
countrywide modernization program,
all Chinese aluminum has been produced
from PFPB cells since the end of
2005. The median of 14 PFC measurements
made in China is used to estimate
the PFC emissions from non-reporting
Chinese primary aluminum producers.
The latest anode effect survey data
is for 2009, with completed surveys
received from facilities producing 60%
of global primary aluminum. Outside
China producers representing 94% of
production responded to the request
for anode effect data. However, since
China produced 35% of global primary
aluminum in 2009, the level of participation
by Chinese producers in the survey
lowered the overall response rate
to 60% of global production. Figure 1
shows the growth in primary aluminum
production from 1990 through 2009 by
production technology type.
Poor economic conditions in 2009
produced the first downturn in global
aluminum production since the anode
effect survey began. Total 2009 primary
aluminum production was 37.1
million metric tons—almost two times
higher than the 19.9 million metric tons
produced in 1990, the baseline year for
calculation of aluminum industry PFC
emissions. The other key feature from
Figure 1 is the increase in the proportion
of PFPB technology. Start-up of
new facilities, operating with modern
PFPB cells and modern computer-controlled
feed technologies, predominate
the growth in primary production since
1990.
Figure 2 shows the key parameters
related to the IAI PFC emissions reduction
objective. The initial global objective
of an 80% reduction in PFC emissions
per metric ton aluminum production
relative to the 1990 baseline was
surpassed in 2006. Results for the most
recent year, 2009, show good progress
toward meeting the 2020 objective of
another halving of PFC emissions from
the 2006 performance, an overall 91%
reduction from 1990 levels.
The remarkable progress in reducing
PFC emissions per metric ton aluminum
has led to a major reduction in
total PFC emissions to the atmosphere,
from 96 million metric tons CO2-e in
1990 to 22 million metric tons in 2009,
even though primary aluminum production
has increased by almost a factor of
two over the same period.
DIRECT MEASUREMENTS OF PFC EMISSIONS
As noted above the aluminum industry
has actively pursued direct measurements
of PFC emissions at production
facilities around the world, using
the measurement protocol established
collaboratively between U.S. EPA
and IAI. The measurements have been
useful in reducing the uncertainty of
global emissions calculation by facilitating
the most accurate Tier 3 calculation
methodology at facilities where
measurements have been made and by
providing data to develop Tier 2 coefficients for those facilities where measurements
have not yet been made. The
measurements also confirm the progress
made in those facilities operating
with the most effective process control
systems, where anode effects have
been almost eliminated. The best PFPB
facilities operate with total PFC emissions
of less than 20 kg CO2-e of PFC
emissions per metric ton aluminum
produced, a factor 10 times better than
the median performance of all PFPB
operators reporting in the 2009 survey.
ADDITIONAL IAI GHG-RELATED OBJECTIVES
Process Focused
In addition to an objective to reduce
(and long-term eliminate) direct greenhouse
gas (PFC) emissions from aluminum
production, the IAI has objectives
to reduce average energy consumption
from smelting and refining processes.
Specifically, these objectives are, first,
a reduction in average electrical energy
to produce one metric ton primary aluminum
by ten percent by 2010 relative
to a 1990 baseline (and therefore indirect
greenhouse gas emissions from
the smelting process), and second, to
reduce energy use per metric ton of alumina
produced by ten percent by 2020
versus 2006 levels (and consequently
direct GHG emissions from fuel consumption
and indirect GHGs from
electrical power usage).
While the data from survey responses
show that, through 2008 (the latest year
for which data is available), the average
electrical energy used to smelt one
metric ton of primary aluminum has
been cut by 4% it does not appear likely
that the 10% reduction objective will
be met by the 2010 year end. The IAI
energy data understates global performance
in that Chinese data is not currently
incorporated into the database.
Chinese producers operate with some
of the most energy-efficient technology
worldwide and if included would
show significantly better energy performance
improvement (the 1990 baseline
being relatively unchanged, due to the
small share of global production represented
by China at that time). However,
it would not be enough to meet the IAI
2010 voluntary objective.
The IAI has also recently established
a new objective to reduce the average
energy for production of a metric ton of
alumina by ten percent by 2020 relative
to the 2006 level. This objective does
take into account the one third of global
alumina production based in China,
through the use of an energy dataset
made available through CRU Group
(www.crugroup.com). The achievement
of this energy reduction goal
would translate into additional reductions
of overall direct greenhouse gas
emissions related to primary aluminum
production.
Product Focus
Recycling of aluminum uses only
five percent of the energy required for
primary production and avoids up to
95% of the greenhouse gas emissions,
with 80 million metric tons of CO2-e saved annually from the recycling
of aluminum products. As part of the
industry’s commitment to stewardship
of aluminum products along the value
chain and sustainable use as well as
production of the metal, the IAI places
major emphasis on increasing further
the rate of recycling to meet growing
future demand for aluminum products.
The institute has developed a mass flow
model to identify current and future recycling
flows—statistical data on current
and historic recycling performance
being particularly hard to collect. The
industry has committed to reporting
regularly on the global recycling performance
derived using the mass flow
model. Results illustrate that around
44 million metric tons of aluminum,
from primary and recycled sources,
ended up in finished products in 2008.
In the same year, approximately one-third
of the metal in products available
on the market was sourced from recycled
(19 million metric tons) and two
thirds from primary (37 million metric
tons) metal. Three quarters of all the
aluminum ever produced (since commercial
production began in the 1880s)
is still in productive use. In 2008 this
stock had grown to about 640 million
metric tons and will someday be available
for recycling at the product end
of life. Globally, aluminum achieves
among the highest material recycling
rates, with up to 90% for transport
and construction applications. Its economic
scrap value and ability to be
recycled continuously makes the aluminum
beverage can the most recycled
container in the world with an average
recycling rate of 60% and over 90% in
some countries—the IAI has recently
developed an objective to increase the
global recycling rate of used beverage
cans from a 2007 average level of 69%
to 75% by the end of 2015.
While increasing efficiency of aluminum
production processes and recycling
of aluminum products saves millions
of metric tons of greenhouse gases
every year, the area with the greatest
potential to reduce emissions is the use
of aluminum products in sustainable
applications, in particular in the light
weighting of transportation vehicles.
The use of 1 kg of aluminum replacing
heavier materials in a car or light
truck can save a net 20 kg of CO2 over
the life of the vehicle. This figure is
even higher for more weight-sensitive
applications (for instance, up to 80 kg
CO2 saved per kg of aluminum used in
trains). The 15 million metric tons of
aluminum currently used in transport
applications every year—cars, buses,
trucks, trains, and ships—can save
up to 300 million metric tons of CO2
and 100 billion liters of crude oil over
the vehicles’ operating life. As car
manufacturers have sought to improve
fuel efficiency, the use of aluminum
has grown every year for the past 30
years; in 1990, the average passenger
car contained between 40 and 80 kg
aluminum; in 2009, the average was
between 120 and 150 kg. Also, while
today aluminum accounts for less than
10% of a car’s total weight it represents
up to 50% of the total material
scrap value—a fact which goes some
way to explain the very high recycling
rates (around 90%) for used aluminum
vehicle components.
To track and quantify the benefits
of aluminum use in transport applications,
the IAI has an objective to monitor
the shipments of aluminum for use
in road, air, rail, and seagoing vehicles.
Results show that aluminum semi-fabricated
products shipped to the transport
sector increased by approximately
22% in the five years from 2003. Projecting
forward based on presumed
growth in demand for transport globally,
greenhouse gas savings from the
use of aluminum for light weighting
vehicles have the potential to double
between 2005 and 2020 to 500 million
metric tons of CO2 per year.
CONCLUSION
The global aluminum industry’s
sustainability initiative, Aluminum
for Future Generations, gives the industry
objectives and timeframes for
continuous improvements in performance
in 14 specific areas that include
greenhouse gas emissions reduction
and energy efficiency in production
processes as well as through sustainable
product use and recycling. Progress
toward objectives is reported annually
by the IAI on its website, www.world-aluminium.org. Excellent progress
has been recorded in the reduction
of PFC emissions, one of the first industrywide
objectives to be adopted.
The initial objective of an 80% reduction
in PFC emissions per metric ton
of primary aluminum produced was
surpassed in 2006 and IAI has adopted
a new challenge of an additional 50%
reduction by the end of 2020 for a total
of over 90% reduction from the 1990
baseline. Currently the best PFPB producers
operate with near zero anode
effects reducing PFC emissions to less
than 20 kg of CO2-e per metric ton of
primary aluminum produced. The industry
is also working to increase the
rate of recycling, already providing a
third of total demand for aluminum.
Recycled aluminum requires only five
percent of the energy as the production
of primary product and produces
only five percent of the greenhouse gas
emissions. The use of aluminum for
light weighting vehicles offers perhaps
the most promising avenue to reduce
emissions, albeit indirectly from one of
the largest contributors of greenhouse
gases, the transportation sector. Thus
the potential for aluminum to be part
of the solution to climate change lies
as much in its use in well-designed, recyclable,
sustainable products as in the
efficiency of its production processes.
REFERENCES
1. IAI, “Aluminium for Future Generations/2009
update” (April 2010), www.world-aluminium.org/cache/fl0000336.pdf.
2. USEPA/IAI, “Protocol for Measurement of
Tetrafluoromethane (CF4) and Hexafluoroethane
(C2F6) Emissions from Primary Aluminum Production”
(April 2010), http://www.epa.gov/highgwp/aluminum-pfc/resources.html#three.
3. Intergovernmental Panel on Climate Change,
“2006 IPCC Guidelines for National Greenhouse
Gas Inventories, Volume 3 Industrial Processes and
Product Use, Chapter 4, Metal Industry Emissions”
(April 2010), http://www.ipcc-nggip.iges.or.jp/public/2006gl/vol3.html.
4. IAI, “The Aluminium Sector Greenhouse Gas Protocol”
(April 2010), http://www.world-aluminium.org/?pg=/Downloads/Publications/Full Publication&path=344.
5. WBCSD/WRI, “The Greenhouse Gas Protocol
Initiative, Aluminum Sector Toolset” (April 2010), http://www.ghgprotocol.org/calculation-tools/aluminumsector.
6. IAA, “Results of the 2009 Anode Effects Survey” (July
2010), www.world-aluminum.org/cache/fl0000339.pdf.
7. Intergovernmental Panel on Climate Change, “IPCC
Second Assessment Climate Change 1995” (April
2010), http://www.ipcc.ch/pdf/climate-changes-1995/ipcc-2nd-assessment/2nd-assessment-en.pdf.
8. Asia Pacific Partnership on Clean Energy and
Climate, “Aluminum Task Force” (April 2010), http://www.asiapacificpar tnership.org/english/tf_aluminium.aspx.
Jerry Marks is with J. Marks & Associates, Lees
Summit, MO 64064; and Chris Bayliss is Director
of Global Projects with International Aluminium
Institute, London, UK SW1 Y 4TE. Mr. Marks can be
reached at jerrymarks@comcast.net. |