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Topic Title: ARTICLE: Optical Absorption, Stability and Structure of NpO2+ Complexes with Dicarboxylic Acids
Topic Summary: G. Tian, et. al., Berkeley National Lab. Information on complexation strength, coordination mode and complex structures
Created On: 5/21/2007 10:25 AM

 5/21/2007 10:25 AM


Lynne Robinson

Posts: 701
Joined: 2/3/2007

Complexation of NpO2+ with oxalic acid (OX),2,2'-oxydiacetic acid (ODA), 2,2'-iminodiacetic acid (IDA) and 2,2'-thiodiacetic acid (TDA), has been studied using spectrophotometry in1 M NaClO4. Both the position and the intensity of the absorption band of NpO2+ at 980 nm are affected by the formation of NpO2+/dicarboxylate complexes, providing useful information on the complexation strength, the coordination mode and the structure of the complexes.

Citation: Tian, G., Rao, L. "Optical Absorption, Stability and Structure of NpO2+ Complexes with Dicarboxylic Acids." MRS Fall Meeting, Boston. 28 November 2005 through 2 December 2005.

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