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Topic Title: ABSTRACT: Microscale Characterization of Uranium(VI) Silicate Solids and Associated Neptunium(V)
Topic Summary: M. Douglas, et. al., Radiochimica Acta. Considerations for assessing the performance of nuclear waste repositories
Created On: 6/27/2007 7:25 AM

 6/27/2007 7:25 AM


Lynne Robinson

Posts: 701
Joined: 2/3/2007

The uranium(VI) silicate phases uranophane, Ca[(UO2)(SiO3OH)]2·5H2O, and sodium boltwoodite, Na[(UO2)(SiO3OH)]·1.5H2O, were synthesized in the presence of small, variable quantities (0.5–2.0 mol % relative to U) of pentavalent neptunium (Np(V), as NpO2+), to investigate the nature of its association with these U(VI) solid phases. The link provided leads to the abstract only. The full article can be purchased from Oldenbourg.

Citation: Douglas, M., Clark, S.B., Friese, J.I., Arey, B.W., Buck, E.C., Hanson, B.D., Utsunomiya, S., and Ewing, R.C. "Microscale Characterization of Uranium(VI) Silicate Solids and Associated Neptunium(V)." Radiochimica Acta. 93 (May 2005): 265-272.

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