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Lynne Robinson Posts: 701 Joined: 2/3/2007
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Ceramics with III-IV pyrochlore compositions, A3+2B4+2O7 (A = Y and rare earth elements; B = Ti, Zr, Sn, or Hf), show a wide range of responses to ion-beam irradiation. To evaluate the role of the B-site cations on the radiation stability ofthe pyrochlore structure-type, Gd2Sn2O7 and Gd2Hf2O7 have been irradiated by1 MeV Kr+. The results are discussed in terms of the ionic size and type of bonding of Sn4+ and Hf4+ and compared to previous results for titanate andzirconate pyrochlores. Link leads to abstract only. The full article can be purchased from the Materials Research Society.
Citation: Lian, J., Ewing, R.C., Wang, L., Helean, K.B. "Ion-Beam Irradiation of Gd2Sn2O7 and Gd2Hf2O7 Pyrochlore: Bond-Type Effect." Journal of Materials Research. 19(5) 2004: 1575-1580 Read Abstract |
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